Topics in Stereochemistry, Volume 4

Topics Stereochemistry by Eliel
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This center is thus stereogenic i.

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The stereogenic atom also known as the stereocenter is usually carbon, as in many biological molecules. However a stereocenter can coincide with any atom, including metals as in many chiral coordination compounds , phosphorus, or sulfur. While the presence of a stereogenic atom describes the great majority of chiral molecules, many variations and exceptions exist.

Topics in Stereochemistry, Volume 22

For instance it is not necessary for the chiral substance to have a stereogenic atom. Examples include 1-bromochlorofluoro adamantane , methylethylphenyl tetrahedrane , certain calixarenes and fullerenes , which have inherent chirality. E - cyclooctene and many ferrocenes have planar chirality. When the optical rotation for an enantiomer is too low for practical measurement, the species is said to exhibit cryptochirality. Even isotopic differences must be considered when examining chirality.

Many biologically active molecules are chiral, including the naturally occurring amino acids the building blocks of proteins and sugars.

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The origin of this homochirality in biology is the subject of much debate. However, there is some suggestion that early amino acids could have formed in comet dust. Enzymes , which are chiral, often distinguish between the two enantiomers of a chiral substrate. One could imagine an enzyme as having a glove-like cavity that binds a substrate. If this glove is right-handed, then one enantiomer will fit inside and be bound, whereas the other enantiomer will have a poor fit and is unlikely to bind.

L -forms of amino acids tend to be tasteless, whereas D -forms tend to taste sweet. Chirality is important in context of ordered phases as well, for example the addition of a small amount of an optically active molecule to a nematic phase a phase that has long range orientational order of molecules transforms that phase to a chiral nematic phase or cholesteric phase. Chirality in context of such phases in polymeric fluids has also been studied in this context. Chirality is a symmetry property, not a property of any part of the periodic table. Thus many inorganic materials, molecules, and ions are chiral.

Quartz is an example from the mineral kingdom.

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Such noncentric materials are of interest for applications in nonlinear optics. In the areas of coordination chemistry and organometallic chemistry , chirality is pervasive and of practical importance. A famous example is tris bipyridine ruthenium II complex in which the three bipyridine ligands adopt a chiral propeller-like arrangement.

Also cf. An Introduction to Biochemistry, Second Edition provides information pertinent to the fundamental aspects of biochemistry. This book presents several analytical methods, including the citrulline reaction for proteins and the diffusion test for acetone.

Organized into two parts encompassing 25 chapters, this edition begins with an overview of the general composition of the organism and the chemical characteristics of the chief organic and inorganic compounds that enter into its structure.

This text then examines the chemical composition of the tissues and physiological systems. Other chapters consider the occurrence and identification of several pathological constituents of urine, which presents features of biochemical interest.

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This book discusses as well the significance and analytical reactions of the bile acids and esters. The final chapter deals with the internal environment, which in the higher animal is represented by the blood and the cerebrospinal and other tissue fluids. This book is a valuable resource for biochemists. The second edition of the book continues to offer a range of pedagogical features maintaining the balanced approach of the text.

The attempts have been made to further strengthen the conceptual understanding by introducing more ideas and a number of solved problems.

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Comprehensive in approach, this text presents a rigorous treatment of organic chemistry to enable undergraduate students to learn the subject in a clear, direct, easily understandable and logical manner. Presented in a new and exciting way, the goal of this book is to make the study of organic chemistry as stimulating, interesting, and relevant as possible.

Beginning with the structures and properties of molecules, IUPAC nomenclature, stereochemistry, and mechanisms of organic reactions, proceeding next to detailed treatment of chemistry of hydrocarbons and functional groups, then to organometallic compounds and oxidation—reduction reactions, and ending with a study of selected topics such as heterocyclic compounds, carbohydrates, amino acids, peptides and proteins, drugs and pesticides, dyes, synthetic polymers and spectroscopy , the book narrates a cohesive story about organic chemistry.

Transitions between topics are smooth, explanations are lucid, and tie-ins to earlier material are frequent to maintain continuity. The book contains over solved problems from simple to really challenging ones with suitable explanations.

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Eliel; Norman L. Sletten, J. Forgot password? About this Item: NY, PDF Request permissions. This is a preview of subscription content, log in to check access. About this Item: Wiley-Interscience,

In addition, over examples and solved problems on IUPAC nomenclature, with varying levels of difficulty, are included. Clearly written and logically organized, the authors have endeavoured to make this complex and important branch of science as easy as possible for students to learn from and for teachers to teach from.

The Purines, Supplement 1. Book The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects — properties, synthesis, reactions, physiological and industrial significance — of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems such as pyridines and oxazoles are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors are recognized authorities, the Chemistry of Heterocyclic Chemistry is considered worldwide as the indispensable resource for organic, bioorganic, and medicinal chemists. Fundamentals of Organic Chemistry: Edition 7.


This seminal series, first edited by Ernest Eliel, responsible for some of the major advances in stereochemistry and the winner of the ACS Priestley Medal in. This seminal series, first edited by Ernest Eliel, responsible for some of the major advances in stereochemistry and the winner of the ACS.

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